Preheat oven to 425 degrees F. Line a sheet pan with parchment paper.
Whisk together the applesauce, steak sauce, honey, mustard and one teaspoon of salt together. Pour evenly over the pork chops being sure to coat both sides. Allow them to marinate while you are preparing the potatoes and onion.
Toss the onions, sweet potatoes and potatoes together on the pan lined with parchment paper. Drizzle the oil over the potato and onion mixture and sprinkle evenly with the remaining one teaspoon of salt, smoked paprika and cayenne pepper. Toss gently to coat. Roast the potatoes in the oven for 20 minutes.
Remove the potatoes and onions from the oven. Gently push them to the edges of the pan so there is enough room in the center of the pan for the pork chops.
Place the pork chops in the center of the pan, topping each chop with more of the applesauce marinade.
Place the pan back in the oven and bake the chops for 20 minutes.
Remove the pan from the oven and check the temperature of each pork chop with an instant read digital thermometer. Continue to bake for an additional 5 minutes, or until the internal temperature of each chop reaches a minimum of 145 degrees F.
Allow the chops to rest for five minutes before serving.